Secretaries of State
- Robert Mercer Taliaferro Hunter (1809–1887), appointed by Jefferson Davis and served July 25, 1861–February 17, 1862.
Secretaries of War
- George Wythe Randolph (1818–1867), appointed by Jefferson Davis and served March 24, 1862–November 15, 1862.
- James Alexander Seddon (1815–1880), appointed by Jefferson Davis and served November 21, 1862–February 5, 1865.