Provisional Confederate Congress
- Thomas Salem Bocock (1815–1891), from Appomattox County, July 1861–February 1862 (president pro tempore, December 1861–February 1862).
- Alexander Robinson Boteler (1815–1892), from Jefferson County (now West Virginia), November 1861–February 1862.
- John White Brockenbrough (1806–1877), from Rockbridge County, May 1861–February 1862.
- Robert Mercer Taliaferro Hunter (1809–1887), from Essex County, May 1861–February 1862.
- Robert Johnston (1818–1885), from Harrison County (now West Virginia), July 1861–February 1862.
- William Hamilton Macfarland (1799–1872), from Richmond, July 1861–February 1862.
- James Murray Mason (1798–1871), from Winchester, July 1861–August 1861.
- Walter Preston (1819–1867), from Washington County, July 1861–February 1862.
- William Ballard Preston (1805–1862), from Montgomery County, July 1861–February 1862.
- Roger Atkinson Pryor (1828–1919), from Petersburg, July 1861–February 1862.
- William Cabell Rives (1793–1868), from Albemarle County, May 1861–February 1862.
- Charles Wells Russell (1818–1867), from Ohio County (now West Virginia), July 1861–February 1862.
- Robert Eden Scott (1808–1862), from Fauquier County, July 1861–February 1862.
- James Alexander Seddon (1815–1880), from Richmond, July 1861–February 1862.
- Waller Redd Staples (1826–1897), from Montgomery County, May 1861–February 1862.
- John Tyler (1790–1862), from Charles City County, August 1861–January 1862.
First and Second Confederate Congresses, House of Representatives
- John Brown Baldwin (1820–1873), from Staunton, February 1862–March 1865.
- Thomas Salem Bocock (1815–1891), from Appomattox County, February 1862–March 1865 (Speaker, First and Second Congresses, 1862–1865).
- Alexander Robinson Boteler (1815–1892), from Jefferson County (now West Virginia), February 1862–February 1864.
- John Randolph Chambliss (1809–1875), from Greensville County, February 1862–February 1864.
- Charles Fenton Collier (1827–1899), from Petersburg, August 1862–February 1864.
- Daniel Coleman Dejarnette (1822–1881), from Caroline County, February 1862–March 1865.
- David Funsten (1819–1866), from Alexandria, December 1863–March 1865.
- Muscoe Russell Hunter Garnett (1821–1864), from Essex County, February 1862–February 1864.
- Thomas Saunders Gholson (1809–1868), from Petersburg, May 1864–March 1865.
- John Goode Jr. (1829–1909), from Bedford County, February 1862–March 1865.
- James Philemon Holcombe (1820–1873), from Albemarle County, February 1862–February 1864.
- Frederick William Mackey Holliday (1828–1899), from Winchester, May 1864–March 1865.
- Albert Gallatin Jenkins (1830–1864), from Cabell County (now West Virginia), February 1862–August 1862.
- Robert Johnston (1818–1885), from Harrison County (now West Virginia), February 1862–March 1865.
- James Lyons (1801–1882), from Richmond, February 1862–February 1864.
- Fayette McMullen (1805–1880), from Scott County, May 1864–March 1865.
- Samuel Augustine Miller (1819–1890), from Kanawha County (now West Virginia), February 1863–March 1865.
- Robert Latané Montague (1819–1880), from Middlesex County, May 1864–January 1865.
- Walter Preston (1819–1867), from Washington County, February 1862–February 1864.
- Roger Atkinson Pryor (1828–1919), from Petersburg, February 1862–April 1862.
- William Cabell Rives (1793–1868), from Albemarle County, May 1864–March 1865.
- Charles Wells Russell (1818–1867), from Ohio County (now West Virginia), February 1862–March 1865.
- William Smith (1797–1887), from Fauquier County, February 1862–April 1863.
- Waller Redd Staples (1826–1897), from Montgomery County, February 1862–March 1865.
- John Tyler (1790–1862), from Charles City County, was elected but died before being seated.
- Robert Henry Whitfield (1814–1868), from Isle of Wight County, May 1864–March 1865.
- Williams Carter Wickham (1820–1888), from Hanover County, May 1864–March 1865.
First and Second Confederate Congresses, Senate
- Allen Taylor Caperton (1810–1876), from Monroe County (now West Virginia), January 1863–March 1865.
- Robert Mercer Taliaferro Hunter (1809–1887), from Essex County, February 1862–March 1865.
- William Ballard Preston (1805–1862), from Montgomery County, February 1862–October 1862.